Palladium-catalyzed asymmetric allylic nucleophilic substitution reactions using chiral tert-butanesulfinylphosphine ligands

DOI: 10.1016/j.tetasy.2009.07.041

Source and publish data:

Tetrahedron Asymmetry p. 1953 - 1956 (2009)

Update date:2022-08-05

Topics:

Authors:

Chen, Junmin

Lang, Feng

Li, Dong

Cun, Linfeng

Zhu, Jin

Deng, Jingen

Liao, Jian

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Article abstract of DOI:10.1016/j.tetasy.2009.07.041

The asymmetric allylic alkylation of racemic 1,3-diphenyl-2-propenyl acetate 3 with dimethyl malonate proceeded smoothly in the presence of lithium acetate, BSA (N,O-bis(trimethylsilyl)acetamide), [Pd(η³-C₃H₅)Cl]_{2
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Full text of DOI:10.1016/j.tetasy.2009.07.041

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