New entry to pyrrolidine homoazasugars: Conversion of D-arabinose into 2,5-anhydro-2,5-imino-D-glucitol via aminohomologation

DOI: 10.1016/S0040-4039(99)01987-5

Source and publish data:

Tetrahedron Letters p. 9375 - 9378 (1999)

Update date:2022-08-04

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Authors:

Dondoni, Alessandro

Perrone, Daniela

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Article abstract of DOI:10.1016/S0040-4039(99)01987-5

The title homoazasugar, also referred as (2R,5S)-bis(hydroxymethyl)-(3R,4R)-dihydroxypyrrolidine, has been synthesized by addition of 2-lithiothiazole to the 2,3,5-tri-O-benzyl-D-arabinofuranose-derived nitrone-hydroxylamine mixture followed by reductive

Full text of DOI:10.1016/S0040-4039(99)01987-5

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