A NEW METHOD FOR THE GENERATION OF A BORON ENOLATE OF AN ESTER - A NEW SYNTHESIS OF 2-DEOXY-D-RIBOSE -

DOI: 10.1246/cl.1982.241

Source and publish data:

Chemistry Letters p. 241 - 244 (1982)

Update date:2022-08-05

Topics: Synthesis Ester Experimental Generation

Authors:

Murakami, Masahiro

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1982.241

A boron enolate of an ester was generated in situ by the treatment of ethoxyacetylene with mercury(II) acetate and diphenylborinic acid, and the boron enolate thus formed further reacted with aldehydes to give β-hydroxyesters and β-acetoxyesters in good yields.The reaction was successfully applied to the stereoselective synthesis of 2-deoxy-D-ribose.

Full text of DOI:10.1246/cl.1982.241

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