Chemistry Letters p. 241 - 244 (1982)
Update date:2022-08-05
Topics: Synthesis Ester Experimental Generation
Murakami, Masahiro
Mukaiyama, Teruaki
A boron enolate of an ester was generated in situ by the treatment of ethoxyacetylene with mercury(II) acetate and diphenylborinic acid, and the boron enolate thus formed further reacted with aldehydes to give β-hydroxyesters and β-acetoxyesters in good yields.The reaction was successfully applied to the stereoselective synthesis of 2-deoxy-D-ribose.
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