Catalytic Asymmetric Synthesis Promoted by a Chiral Zirconate: Highly Enantioselective Allylation of Aldehydes

DOI: 10.1016/0040-4039(95)01627-T

Source and publish data:

Tetrahedron Letters p. 7897 - 7900 (1995)

Update date:2022-07-30

Topics:

Authors:

Bedeschi, Paolo

Casolari, Sonia

Costa, Anna L.

Tagliavini, Emilio

Umani-Ronchi, Achille

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Article abstract of DOI:10.1016/0040-4039(95)01627-T

A new chiral Lewis acid catalyst, , is prepared from (R) or (S)-BINOL and commercially available Zr(OiPr)4*iPrOH; it efficently promotes the enantioselective allylation of aldehydes by allyltributyltin in shorter times and at lower temperatures with respect to related catalysts.

Full text of DOI:10.1016/0040-4039(95)01627-T

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