Stereocontrolled synthesis of substituted tetrahydropyrans from 1,3-dioxan-4-ones

DOI: 10.1016/0040-4039(95)02114-0

Source and publish data:

Tetrahedron Letters p. 141 - 144 (1996)

Update date:2022-08-04

Topics:

Authors:

Petasis, Nicos A.

Lu, Shao-Po

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Article abstract of DOI:10.1016/0040-4039(95)02114-0

Conversion of aldehydes to 1,3-dioxan-4-ones, followed by methylenation with dimethyl titanocene gave the corresponding vinyl acetals which could undergo a stereocontrolled aluminum-mediated rearrangement to afford substituted tetrahydropyrans.

Full text of DOI:10.1016/0040-4039(95)02114-0

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