Tetrahedron Letters p. 6517 - 6520 (1988)
Update date:2022-07-30
Topics:
Crombie, Leslie
Rainbow, Linda J.
The use of samarium di-iodide in place of sodium metal for the ring scission of cyclic β-halogeno-ethers drastically alters the stereochemistry of the resulting olefinic alcohols: using the method, highly stereoselective syntheses of enynols in (Z)- and (E)-forms are reported.
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