
Journal of the Chemical Society. Chemical communications p. 969 - 970 (1981)
Update date:2022-08-03
Topics:
Sekine, Mitsuo
Kume, Akiko
Hata, Tsujiaki
Diethyl 1-hydroxy-3-phenyl-1-trimethylsilylpropylphosphonate (5) underwent silicon-tin rearrangement with tributyltin alkoxides to afford the 1-silyloxy-1-stannylpropylphosphonate (6) in high yield; the 1-hydroxypropylphosphonate (8) was converted by treatment with a stannylating agent into the ketone (9).
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