Journal of Organic Chemistry p. 7428 - 7436 (2017)
Update date:2022-08-04
Topics:
Zhu, Yan
Gong, Juwen
Wang, Yonghui
A novel and efficient free-radical-promoted copper-catalyzed decarboxylative alkylation of α,β-unsaturated carboxylic acids with ICH2CF3 and its analogues has been developed. This methodology provides a convenient access to the synthesis of allylic trifluoromethyl and β-CF3 ketone containing compounds as well as other biologically useful fluorinated molecules and materials.
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