DIRECT PHOTOLYSIS AT 185 NM OF CYCLOPENTENE AND 2-NORBORNENE. A NOVEL REACTION CHANNEL FOR ?, ?* EXCITED SINGLET ALKENE

DOI: 10.1246/cl.1982.1045

Source and publish data:

Chemistry Letters p. 1045 - 1048 (1982)

Update date:2022-08-03

Topics: Alkene Photolysis Product Analysis Quantum Yield Excitation wavelength Cyclopentene Transient species

Authors:

Inoue, Yoshihisa

Mukai, Toshio

Hakushi,Tadao

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Article abstract of DOI:10.1246/cl.1982.1045

Upon direct irradiation at 185 nm, the title compounds undergo hydrogen abstraction from the solvent via a ?, ?* excited singlet state as well as skeletal rearrangement via a ?,R(3s) Rydberg excited state.

Full text of DOI:10.1246/cl.1982.1045

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