Chemical and Pharmaceutical Bulletin p. 1171 - 1175 (2000)
Update date:2022-08-05
Topics:
Yamada
Suemune
The reactivity of 3-substituted 4-methyl-4-(3-oxobutyl)-2-cyclohexen-1-ones (1) in the presence of a combination of a Lewis acid and a 1,2-diol was studied. The results suggest several factors that influence 6-membered ring formation, including two types of intramolecular aldol reaction and intramolecular 1,4-addition, due to the C3-substituent, Lewis acid, and the presence of diol. In this study, novel methodology to prepare two types of decalin skeleton could be developed.
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Doi:10.1039/c39930001874
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(2016)Doi:10.1039/b001905o
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(2001)
