Tetrahedron p. 1931 - 1936 (1980)
Update date:2022-08-05
Topics:
Leroy, J.
Bensoam, J.
Humiliere, M.
Wakselman, C.
Mathey, F.
Monofluorophosphoranes R3MePF are used in exchange reactions to prepare monofluorinated organic compounds.Tri(n-butyl)methylfluorophosphorane (n-Bu3MePF), easily available, is the most reactive.In solvents of low polarity or even in non-polar solvents, it reacts at -70 deg C with alkyl sulphonates and halides activated by ester, ketone, or ether functions.Thus, fluorinated epoxides can be obtained directly by exchange from their chlorinated or brominated homologues.
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