Beilstein Journal of Organic Chemistry p. 2005 - 2011 (2016)
Update date:2022-07-30
Topics:
Wilson, Kirsty L.
Kennedy, Alan R.
Murray, Jane
Greatrex, Ben
Jamieson, Craig
Watson, Allan J. B.
Pd-catalysed C-C bond formation is an essential tool within the pharmaceutical and agrochemical industries. Many of these reactions rely heavily on polar aprotic solvents; however, despite their utility, these solvents are incompatible with the drive towards more sustainable chemical synthesis. Herein, we describe the scope and limitations of an alternative to DMF derived from renewable sources (Cyrene) in Sonogashira cross-coupling and Cacchi-type annulations.
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