Tetrahedron Letters p. 5913 - 5916 (1992)
Update date:2022-08-05
Topics:
Esker, John L.
Newcomb, Martin
N'-Acyl-N-hydroxypyridine-2-thione carbamates react in radical chain reactions to give the title radicals which can decarboxylate or react by intramolecular hydrogen atom transfer; the competing reaction pathways are controlled by the structure of the alkyl group and the conformation of the precursor which can be influenced by addition of a Lewis acid.
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