Palladium(0) catalysed rearrangements of allylic sulfoximines to allyl sulfinimidic acid esters and optically active N-Cbz protected γ-amino- enomes

DOI: 10.1016/S0040-4039(98)01847-4

Source and publish data:

Tetrahedron Letters p. 8499 - 8502 (1998)

Update date:2022-08-02

Topics:

Authors:

Pyne, Stephen G.

David, Dorothy M.

Dong, Zemin

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Article abstract of DOI:10.1016/S0040-4039(98)01847-4

N-Tosyl allylic sulfoximines undergo rearrangement to allyl sulfinimidic acid esters in the presence of bidentate chiral ligands while N-Cbz allylic sulfoximines give optically active N-Cbz protected γ-amino-enones.

Full text of DOI:10.1016/S0040-4039(98)01847-4

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