Synthesis of (Z)-3-deoxy-3-(1,2,3,4,5,6-tetradeoxy-3,6-imino-L-arabino-hexitol-1-C-ylidene)-D -xylo-hexose derivatives. First examples of homo-(1→3)-C-linked iminodisaccharides1

Article abstract of DOI:10.1080/07328300008544099

Cross-aldolisation of 3,6-[(tert-butoxy)carbonyl]imino-2,3,6-trideoxy-4,5-O-isopropylidene-L-arabino-h exose (10) with 1,6-anhydro-2-O-benzyl-3-deoxy-β-D-erythro-hexopyrano-4-ulose (6) generates, after water elimination, a single enone 11 that is reduced

Full text of DOI:10.1080/07328300008544099

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Journal of Carbohydrate Chemistry
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Synthesis of (Z)-3-Deoxy-3-
(1,2,3,6-Tetradeoxy-3,6-Imino-
L-Arabino-Hexitol-1-C-Ylidene)-
D-Xylo-Hexose Derivatives. First
Examples Of Homo-(1→3)-C-Linked
Iminodisaccharides.
Francesca Cardona, Inmaculada Robina & Pierre Vogel
a Section de Chimie de l'Université de Lausanne, BCH,
CH-1015-Lausanne-Dorigny, Switzerland
b Departamento de Química Orgánica, Universidad de Sevilla,
Apartado 557, E-41071 Sevilla, Spain
Version of record first published: 07 Mar 2008
To cite this article: Francesca Cardona, Inmaculada Robina & Pierre Vogel (2000): Synthesis
of (Z)-3-Deoxy-3-(1,2,3,6-Tetradeoxy-3,6-Imino-L-Arabino-Hexitol-1-C-Ylidene)-D-Xylo-
Hexose Derivatives. First Examples Of Homo-(1→3)-C-Linked Iminodisaccharides., Journal of
Carbohydrate Chemistry, 19:4-5, 555-571
To link to this article: http://dx.doi.org/10.1080/07328300008544099
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