Asymmetric Synthesis of α,α-dichlorosulphoxides from Substituted Thioacetates and Sodium Hypochlorite in β-Cyclodextrin Complexes

DOI: 10.1039/c39890000342

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 342 - 343 (1989)

Update date:2022-08-02

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Authors:

Rao, K. Rama

Sattur, P. B.

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Article abstract of DOI:10.1039/c39890000342

The reaction of β-cyclodextrin complexes of substituted thioacetates (1) with sodium hypochlorite in aqueous medium gives optically active α,α-dichlorosulphoxides (2) in good yields with an enantiomeric excess (e.e.) of up to 53percent.

Full text of DOI:10.1039/c39890000342

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