Chemistry Letters p. 129 - 132 (1993)
Update date:2022-08-05
Topics:
Hatsui, Toshihide
Takeshita, Hitoshi
Quadricyclane was photooxygenated with singlet oxygen generated under Rose-Bengal-sensitized conditions to a dioxetane, which in turn gave 2-cyclopentene-1,4-dicarbaldehyde and 5-norbornene-cis-2,3-exo-diol.For the mechanism to form the dioxetane, an involvement of a <2?+2?+2?> electrocyclic process is proposed.
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