REACTION OF DICOBALT OCTACARBONYL WITH ACETYLENE AND CARBON MONOXIDE AT LOW TEMPERATURE AND PRESSURE: FORMATION OF CYCLIC ENONE PRODUCTS

DOI: 10.1016/0022-328X(84)80487-8

Source and publish data:

Journal of Organometallic Chemistry p. 435 - 446 (1984)

Update date:2022-08-04

Topics:

Authors:

Schore, N. E.

Belle, B. E. la

Knudsen, M. J.

Hope, H.

Xu, X-J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(84)80487-8

Dicobalt octacarbonyl is shown to react with acetylene and carbon monoxide under mild conditions in dimethoxyethane or benzene to produce, in low yields, bicyclo<3.3.0>octa-3,7-diene-2,6-dione, benzoquinone, and the cyclopentadienone-derived products 3a,4,7,7a-tetrahydro-2,7-methanoindene-1,10-dione, 1-indanone, tetracyclo<5.5.2.0^2,60^8,12>tetradeca-4,10,13-triene-3,9-dione, and tetracyclo<5.5.2.0^2,60^8,12>tetradeca-4,9,13-triene-3,11-dione. Possible mechanisms for the formation of these products are discussed.

Full text of DOI:10.1016/0022-328X(84)80487-8

Products guided by the article

Product name:endo-tricyclo<5.2.1.0^2,6>deca-4,8-dien-3,10-dione

Cas No:30273-54-2

R&D Labs maybe for 30273-54-2

Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
HaiNan Periwinkle Pharmaceutical Co.,Ltd.

website:http://www.cchpharm.com/en/index.html

Contact:020-82208978

Address:Gongye road,Wuzhishan city,HaiNan province
Chengdu CSH Pharmaceutical Co.,ltd

Contact:+86-(28)-85321971

Address:Block B,New Hope Int. Tian Fu New District, Chengdu, Sichuan, China
NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road

Relevant to this article

Doi:10.1021/ja01094a023
(1965)
First synthesis of a rearranged neo-clerodane diterpenoid. Development of totally regioselective trisubstituted furan ring assembly and medium-ring alkylation tactics for efficient access to (-)-teubrevin G [15]

Doi:10.1021/ja002450x
(2000)
Doi:10.1016/S0040-4020(01)98732-0
(1970)
Probing the stereoselectivity of the Heck arylation of endocyclic enecarbamates with diazonium salts. Concise syntheses of (2S,5R)-phenylproline methyl ester and Schramm's C-azanucleoside.

Doi:10.1021/ol027268a
(2003)
Vibrational study of the salicylate interaction with metallic ions and surfaces

Doi:10.1016/S1386-1425(00)00328-0
(2000)
Ligand substitution kinetics in M(CO)₄(η^2:2-norbornadiene) complexes (M=Cr, Mo, W): Displacement of norbornadiene by bis(diphenylphosphino)alkanes

Doi:10.1016/S0022-328X(99)00458-1
(1999)

Article Doi