Journal of Organometallic Chemistry p. 435 - 446 (1984)
Update date:2022-08-04
Topics:
Schore, N. E.
Belle, B. E. la
Knudsen, M. J.
Hope, H.
Xu, X-J.
Dicobalt octacarbonyl is shown to react with acetylene and carbon monoxide under mild conditions in dimethoxyethane or benzene to produce, in low yields, bicyclo<3.3.0>octa-3,7-diene-2,6-dione, benzoquinone, and the cyclopentadienone-derived products 3a,4,7,7a-tetrahydro-2,7-methanoindene-1,10-dione, 1-indanone, tetracyclo<5.5.2.02,608,12>tetradeca-4,10,13-triene-3,9-dione, and tetracyclo<5.5.2.02,608,12>tetradeca-4,9,13-triene-3,11-dione. Possible mechanisms for the formation of these products are discussed.
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