Studies on the synthesis of myriaporones: Stereoselective synthesis of the C5-C13 fragment starting from D-glucose via regioselective reductive opening of methoxybenzylidene acetal

DOI: 10.1248/cpb.48.1761

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1761 - 1765 (2000)

Update date:2022-08-03

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Authors:

Zheng Zheng

Yamauchi

Dei Dei

Yonemitsu

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Article abstract of DOI:10.1248/cpb.48.1761

A stereoselective synthesis is described of the C5-C13 fragment (4) of myriaporone 4 (1) starting from D-glucose by a coupling of the C5-C9 aldehyde (5), prepared using a regioselective reductive ring-opening of methoxybenzylidene acetal, with the C10-C13 iodoolefin (6).

Full text of DOI:10.1248/cpb.48.1761

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