Journal of the American Chemical Society p. 2652 - 2662 (1989)
Update date:2022-08-04
Topics:
Gassman, Paul G.
Bonser, Steven M.
Mlinaric-Majerski, Kata
trans-Bicyclo<4.1.0>hept-3-ene, 7-methyl-trans-bicyclo<4.1.0>hept-3-ene, and 7,7-dimethyl-trans-bicyclo<4.1.0>hept-3-ene have been synthesized.Comparison of their ease of oxidation with the ease of oxidation of the analogous cis-bicyclo<4.1.0>hept-3-enes has been made.Both the thermal and transition-metal complex promoted rearrangements of the trans-bicyclo<4.1.0>hept-3-enes have been studied.These systems thermally convert to the cis-bicyclo<4.1.0>hept-3-enes above 100 deg C and are catalytically rearranged at ambient temperature.Trans to cis isomerization alsooccurs at ambient temperature under photoinduced single electron transfer conditions.
View MoreChangzhou Anyi Biochem Co., Ltd.(expird)
Contact:+86-519-88836158
Address:no,51 caoda
SHAANXI FUJIE PHARMACEUTICAL CO.,LTD
website:http://www.fujiepharm.com
Contact:+86-29-63650906
Address:Yuanqu Yi Road, Qinghe Food Industrial Park, Sanyuan County, Shaanxi Province, China
Contact:+86-10-67147360/67107388
Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
zhenjiang runjing high purity chemical co ltd
Contact:+86-511-83361155
Address:No.8.haixi road,international chemical park
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD
website:http://www.czyys.com
Contact:0086-519-88802789
Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Doi:10.1016/j.tetlet.2007.07.183
(2007)Doi:10.3906/kim-1802-18
(2018)Doi:10.1002/chem.200901386
(2009)Doi:10.1021/jm900862n
(2009)Doi:10.1016/j.jorganchem.2015.03.002
(2015)Doi:10.1371/journal.pone.0187767
(2017)