Synthetic Photochemistry. XXXIV. Synthetic Strategy of 5-8-5-Membered Tricyclic Higher Terpenoids Based on the Condensation of Two Optically-Active Iridoids, C10-Synthons Obtained from Photo-Cycloadduct of Methyl 2,4-Dioxo-pentanoate-Isoprene, and Its App

DOI: 10.1246/bcsj.59.1109

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Bulletin of the Chemical Society of Japan p. 1109 - 1124 (1986)

Update date:2022-09-26

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Authors:

Kato, Nobuo

Nakanishi, Kohji

Takeshita, Hitoshi

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Article abstract of DOI:10.1246/bcsj.59.1109

One of the photocycloadducts obtained during methyl 2,4-dioxopentanoate to isoprene was converted to optically active iridoids.Using a CrCl2 reductive-couping reaction, proper combinations of two kinds of enantiomeric iridoids, 1-iriden-7-al and 9-benzylo

Full text of DOI:10.1246/bcsj.59.1109

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