Journal of Organic Chemistry p. 2226 - 2227 (1981)
Update date:2022-07-30
Topics:
Mitani, Michiharu
Takayama, Mimatsu
Koyama, Kikuhiko
Ethyl azidoformate (2) was thermolyzed in the presence of metalloporphyrins.CoTPP accelerated the decomposition rate of 2 and resulted in the preferential formation of the hydrogen-abstraction product (urethane).On the other hand, NiTPP and CuTPP had no influence on the decomposition behavior of 2.
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