Journal of the Chemical Society. Chemical communications p. 287 - 288 (1994)
Update date:2022-08-03
Topics:
Fukuzumi, Shunichi
Noura, Souta
Thermal reduction of 1-methylquinolinium ion by tributyltin hydride occurs via a polar mechanism to yield 1-methyl-1,2-dihydroquinoline selectively, while the photoreduction of 1-methylquinolinium ion derivatives by tributyltin hydride and tris(trimethylsilyl)silane proceeds via photoinduced electron transfer from the metal hydrides to the singlet excited states of 1-methylquinolinium ion derivatives to yield the corresponding 1,4-dihydroquinolines exclusively.
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