Journal of Organic Chemistry p. 3255 - 3258 (1991)
Update date:2022-08-03
Topics:
Durandetti, Sylvie
Sibille, Soline
Perichon, Jacques
An efficient electrosynthesis of cyclopropanes from gem-dibromoalkanes and alkenes is achieved in a one-compartment cell fitted with a sacrificial zinc anode.The part played by the anodically generated Zn(II) in the coupling reaction is pointed out, and evidence for the existence of an organozinc species as intermediate is presented.
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