Tetrahedron Letters (2019)
Update date:2022-08-02
Topics:
Li, Gang-Jian
Pan, You-Lu
Liu, Yan-Ling
Xu, Hai-Feng
Chen, Jian-Zhong
It was reported to develop a simple and convenient method for the Ni/NHC-catalyzed cross-coupling of methyl sulfinates and amines without an acid/base to afford secondary or tertiary sulfinamides in moderate to good yields. The method can provide the desired products with broad substrate scope, good chemoselectivity and good functional group compatibility. The presented approach may enrich the Ni/NHC catalyst system and promote the applications of methyl sulfinates in the organic sulfur chemistry.
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Doi:10.1039/c8dt03007c
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