31401-17-9

Basic information

• Product Name: methyl p-methoxybenzenesulphinate
• Synonyms: methyl p-methoxybenzenesulphinate
• CAS NO: 31401-17-9
• Molecular Weight: 186.232
• Mol File: 31401-17-9.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: methyl p-methoxybenzenesulphinate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl p-methoxybenzenesulphinate(31401-17-9)
• EPA Substance Registry System: methyl p-methoxybenzenesulphinate(31401-17-9)

Safety Data

• Hazardous Substances Data: 31401-17-9(Hazardous Substances Data)

Upstream product

• 1879-16-9 1-methoxy-4-methylsulfanyl-benzene 
• 67-56-1 methanol 
• 696-63-9 4-Methoxybenzenethiol 
• 106-45-6 para-thiocresol 
• 1709-60-0 4-methoxybenzenesulfinic acid 
• 459-64-3 4-methoxybenzenediazonium tetrafluoroborate 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 98-68-0 4-methoxy-phenyl-sulphonyl chloride 
• 1950-68-1 4-methoxybenzenesulfonyl hydrazide 
• 124-38-9 carbon dioxide 
• 1129-26-6 4-methoxybenzene sulfonamide 
• 100-52-7 benzaldehyde 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 1423047-90-8 N-tosyl-α-(tributylstannyl)benzylamine 

Downstream Products

• 1017238-69-5 N-(4-methoxyphenylsulfinyl)-N-(tert-butyl)amine 
• 1017238-70-8 N-(4-methoxyphenylsulfinyl)-N,N-diethylamine 
• 335215-12-8 1-((4-methoxyphenyl)sulfonyl)pyrrolidine 
• 92100-00-0 N,N-Diethyl-4-methoxybenzenesulfonamide 
• 5335-87-5 4,4'-dimethoxyphenyl disulfide 
• 6214-19-3 methyl p-methoxybenzenesulfonate 
• 32916-20-4 1-methoxy-4-((trifluoromethyl)sulfinyl)benzene 
• 10381-41-6 1-methoxy-4-(4-toluenesulfinyl)benzene 
• 951-92-8 1-methoxyl-4-(phenylsulfinyl)benzene 
• 1774-36-3 bis(4-methoxyphenyl) sulfoxide 
• 75736-88-8 1-chloro-4-((4-methoxyphenyl)sulfinyl)benzene 
• 1369434-68-3 (E)-1-methoxy-4-(styrylsulfinyl)benzene 

Relevant articles and documents

Ni/NHC-catalyzed cross-coupling of methyl sulfinates and amines for direct access to sulfinamides

It was reported to develop a simple and convenient method for the Ni/NHC-catalyzed cross-coupling of methyl sulfinates and amines without an acid/base to afford secondary or tertiary sulfinamides in moderate to good yields. The method can provide the desired products with broad substrate scope, good chemoselectivity and good functional group compatibility. The presented approach may enrich the Ni/NHC catalyst system and promote the applications of methyl sulfinates in the organic sulfur chemistry.

Direct synthesis of sulfinic esters via ultrasound accelerated tandem reaction of thiols and alcohols with N-bromosuccinimide

The direct transformation of various thiols and simple alcohols with N-bromosuccinimide into sulfinic esters has been investigated by using different categories of base/acidic catalysts as well as co-solvents under varied reaction conditions. The reaction was found out to afford the sulfinic esters with high yields in the absence of catalysts, especially within the shorter time under the acceleration of ultrasonic irradiation than under the longer-lasting conventional stirring conditions.

Preparation method of sulfinate compound

The invention relates to a preparation method of a sulfinate compound shown as a formula (III), which comprises the following steps: by using a sulfonyl hydrazine compound shown as a formula (I) and alcohol shown as a formula (II) as raw materials, adding