Kinetics and Mechanism of Isocyanide-Promoted Carbene Insertion into the Aryl Substituent of an N-Heterocyclic Carbene Ligand in Ruthenium-Based Metathesis Catalysts

DOI: 10.1021/acs.organomet.7b00342

Source and publish data:

Organometallics p. 3043 - 3052 (2017)

Update date:2022-07-31

Topics:

Authors:

Griffiths, Justin R.

Hofman, Elan J.

Keister, Jerome B.

Diver, Steven T.

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Article abstract of DOI:10.1021/acs.organomet.7b00342

In situ IR spectroscopy was used to study the kinetics of addition of L = alkyl and aryl isocyanides to the Grubbs second-generation carbene complex Ru(H₂IMes)(CHPh)(PCy₃)Cl₂ (H₂IMes = 1,3-dimesityl-4,5-dihydroi

Full text of DOI:10.1021/acs.organomet.7b00342

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