Anchimerically Assisted Demethylation of Methyl Ethers in Inositol Derivatives with an AlCl3-NaI System

DOI: 10.1246/cl.1990.1881

Source and publish data:

Chemistry Letters p. 1881 - 1884 (1990)

Update date:2022-09-26

Topics:

Authors:

Akiyama, Takahiko

Takechi, Naoto

Shima, Hiroaki

Ozaki, Shoichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.1881

Investigated are AlCl3 and NaI catalyzed chemoselective demethylation reactions of methyl ethers of partly protected inositol derivatives, reactions which are greatly promoted by vicinal OH group and proceed in preference to the cleavage of the cis cyclohexylidene moiety.

Full text of DOI:10.1246/cl.1990.1881

Products guided by the article

Product name:C₁₉H₂₆O₈S

Cas No:32590-37-7

R&D Labs maybe for 32590-37-7

Hangzhou Chemfar Ltd.

Contact:+86-571-87859231, 87859237, 87859239

Address:1606,Huarong Times Mansion, No.3880 Jiangnan Avenue, Binjiang District, Hangzhou, China, 310053
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.
Shijiazhuang Haitian Amino Acid Co., Ltd.

Contact:+86-311-88908111

Address:Shijiazhuang Hebei province,China

Relevant to this article

Isolation, structural and spectroscopic investigations of complexes with tridentate [O,P,O] and [O,O,O] donor ligands

Doi:10.1039/b005693f
(2000)
An improved synthesis of chiral α-(4-bromobenzyl)alanine ethyl ester and its application to the synthesis of LFA-1 antagonist BIRT-377

Doi:10.1021/jo0013913
(2001)
Diastereocontrolled synthesis of enantiopure trans- and cis-5-allylprolinols via a ring-contraction protocol

Doi:10.1055/s-2001-9731
(2001)
Direct access to cobaltacycles via C-H activation: N-chloroamide- enabled room-temperature synthesis of heterocycles

Doi:10.1021/acs.orglett.7b02632
(2017)
σσ* transition in anti, cisoid alternating oligosilanes: Clear-cut evidence for suppression of conjugation effect by a cisoid turn

Doi:10.1021/ja034500e
(2003)
Reactions Catalysed by a Binuclear Copper Complex: Relay Aerobic Oxidation of N-Aryl Tetrahydroisoquinolines to Dihydroisoquinolones with a Vitamin B1 Analogue

Doi:10.1002/chem.201604750
(2017)

Article Doi