Anchimerically Assisted Demethylation of Methyl Ethers in Inositol Derivatives with an AlCl3-NaI System

DOI: 10.1246/cl.1990.1881

Source and publish data:

Chemistry Letters p. 1881 - 1884 (1990)

Update date:2022-09-26

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Authors:

Akiyama, Takahiko

Takechi, Naoto

Shima, Hiroaki

Ozaki, Shoichiro

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Article abstract of DOI:10.1246/cl.1990.1881

Investigated are AlCl3 and NaI catalyzed chemoselective demethylation reactions of methyl ethers of partly protected inositol derivatives, reactions which are greatly promoted by vicinal OH group and proceed in preference to the cleavage of the cis cyclohexylidene moiety.

Full text of DOI:10.1246/cl.1990.1881

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