Anchimerically Assisted Demethylation of Methyl Ethers in Inositol Derivatives with an AlCl3-NaI System

DOI: 10.1246/cl.1990.1881

Source and publish data:

Chemistry Letters p. 1881 - 1884 (1990)

Update date:2022-09-26

Topics:

Authors:

Akiyama, Takahiko

Takechi, Naoto

Shima, Hiroaki

Ozaki, Shoichiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1990.1881

Investigated are AlCl3 and NaI catalyzed chemoselective demethylation reactions of methyl ethers of partly protected inositol derivatives, reactions which are greatly promoted by vicinal OH group and proceed in preference to the cleavage of the cis cyclohexylidene moiety.

Full text of DOI:10.1246/cl.1990.1881

Products guided by the article

Product name:C₁₉H₂₆O₈S

Cas No:32590-37-7

R&D Labs maybe for 32590-37-7

CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone
Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Jiangxi Biochem Co.,Ltd

Contact:86-791-86629460

Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China

Relevant to this article

Isolation, structural and spectroscopic investigations of complexes with tridentate [O,P,O] and [O,O,O] donor ligands

Doi:10.1039/b005693f
(2000)
An improved synthesis of chiral α-(4-bromobenzyl)alanine ethyl ester and its application to the synthesis of LFA-1 antagonist BIRT-377

Doi:10.1021/jo0013913
(2001)
Diastereocontrolled synthesis of enantiopure trans- and cis-5-allylprolinols via a ring-contraction protocol

Doi:10.1055/s-2001-9731
(2001)
Direct access to cobaltacycles via C-H activation: N-chloroamide- enabled room-temperature synthesis of heterocycles

Doi:10.1021/acs.orglett.7b02632
(2017)
σσ* transition in anti, cisoid alternating oligosilanes: Clear-cut evidence for suppression of conjugation effect by a cisoid turn

Doi:10.1021/ja034500e
(2003)
Reactions Catalysed by a Binuclear Copper Complex: Relay Aerobic Oxidation of N-Aryl Tetrahydroisoquinolines to Dihydroisoquinolones with a Vitamin B1 Analogue

Doi:10.1002/chem.201604750
(2017)

Article Doi