Journal of the Chemical Society - Faraday Transactions p. 273 - 277 (1991)
Update date:2022-08-05
Topics:
Kumar, M. Ravi
Lingam, K. V.
Rao, T. K. Gundu
Radicals trapped in a γ-irradiated single crystal of potassium hydrogen thiodiacetate have been investigated using the techniques of EPR and ENDOR.A radical of the type HO2C-CH2-S-CH-CO2H was observed and analysed.The second radical could not be analysed, owing to overlap the spectrum and only information about the g factors could be obtained.The third radical observed was of the type RCH2-S, formed by the scission of the S-C bond, and was observably only at low temperatures (below -100 deg C), and was characterized by highly anisotropic g factors.
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