Tetrahedron Letters p. 669 - 672 (1994)
Update date:2022-08-04
Topics:
Chang, Sukbok
Heid, Richard M.
Jacobsen, Eric N.
Chiral (salen)Mn(III)Cl complexes catalyze epoxidation of cyclic 1,3-dienes with moderate-to-good enantioselectivity. A new catalyst (2), bearing sterically hindered and electron donating (OSi(iPr)3 (OTIPS) substituents, induces up to 12% higher selectivity than the previously-reported tert-butyl substituted analog 1.
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