Tetrahedron Letters p. 8023 - 8027 (1999)
Update date:2022-08-03
Topics:
D'Accolti, Lucia
Fiorentino, Michele
Fusco, Caterina
Rosa, Angela M.
Curci, Ruggero
A comparison of the diastereoselectivity and the chemoselectivity (epoxidation versus allylic oxidation) attained in the oxidation of cyclopentenols using dimethyldioxirane and methyl(trifluoromethyl)dioxirane is reported. The results indicate that with both dioxiranes diastereoselective epoxidation of allylic cyclopentenols is accompanied by competitive allylic oxidation to the corresponding enone; for the latter a likely rationale is proposed.
View Morejiangsu senxuan pharmaceutical and chemical co.,ltd
Contact:86-523-87982810
Address:hongqiao industrial zone,taixing,jiangsu china
shanghai jinshan pharmaceutical Co.,Ltd
Contact:021-57363011，13681638167
Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Contact:+86-28-88523492
Address:714rooms of Time Square, Pujiang County
shijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
CGeneTech (Suzhou, China) Co., Ltd.
Contact:+86-512-62956962
Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
Doi:10.1021/jo00978a021
(1972)Doi:10.1016/S0040-4039(00)85767-6
(1982)Doi:10.1002/oms.1210180306
(1983)Doi:10.1021/acs.jnatprod.5b01012
(2016)Doi:10.1021/ja00302a010
(1985)Doi:10.1021/jm00186a014
(1980)
