Tetrahedron Letters p. 8023 - 8027 (1999)
Update date:2022-08-03
Topics:
D'Accolti, Lucia
Fiorentino, Michele
Fusco, Caterina
Rosa, Angela M.
Curci, Ruggero
A comparison of the diastereoselectivity and the chemoselectivity (epoxidation versus allylic oxidation) attained in the oxidation of cyclopentenols using dimethyldioxirane and methyl(trifluoromethyl)dioxirane is reported. The results indicate that with both dioxiranes diastereoselective epoxidation of allylic cyclopentenols is accompanied by competitive allylic oxidation to the corresponding enone; for the latter a likely rationale is proposed.
View Morewebsite:https://sdjingyuan.lookchem.com/
Contact:86-531-82687998
Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
RongCheng K&S Chemical Co.,Ltd
Contact:0631-7336369
Address:rongcheng ,shandong province china
AllyChem Co., Ltd., Dalian, China（BBChem）
Contact:+86-411-62313318/62313328
Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Jinan Jiaquan Chemical Co.,Ltd
Contact:+86-531-62318366
Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Contact:+86-535-8888888
Address:No.161 Haishi Rd.
Doi:10.1021/jo00978a021
(1972)Doi:10.1016/S0040-4039(00)85767-6
(1982)Doi:10.1002/oms.1210180306
(1983)Doi:10.1021/acs.jnatprod.5b01012
(2016)Doi:10.1021/ja00302a010
(1985)Doi:10.1021/jm00186a014
(1980)
