Bulletin of the Chemical Society of Japan p. 791 - 795 (1984)
Update date:2022-08-03
Topics:
Miyagi, Yo
Maruyama, Kazuhiro
Tanaka, Nobuo
Sato, Mamoru
Tomizu, Toshinori
et all.
Upon irradiation a regio- and stereoselective cycloaddition occured intramolecularly between two acyl-1,4-benzoquinone moieties connected by a polymethylene bridge.The regio- and stereoselectivities are different from those of the corresponding intermolecular cycloaddition; this was interpreted in terms of the Diels-Alder reaction between an acyl-1,4-benzoquinone moiety and a photochemically produced dienol.
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