
Chemistry Letters p. 13 - 14 (1995)
Update date:2022-08-04
Topics:
Horiuchi, C. Akira
Hosokawa, Haruomi
Kanamori, Miyuki
Muramatsu, Yukiko
Ochiai, Keiko
Takahashi, Eiji
Reaction of 1,3-cycloalkadienes (cyclopentadiene, cyclohexadiene, and cycloheptadiene) with iodine-cerium(IV) ammonium nitrate in alcohols, gave the corresponding regiospecific trans-2-alkoxy-1-iodo compounds as major products accompanied with 1,4-dialkoxy compounds as by-products.In the case of CH3CN-H2O as solvent, trans-iodohydrins were obtained.Thus the reaction of cyclic and acyclic i671,3-diene derivatives using this synthetic method afforded the 1,2-addition alkoxyiodo compounds preferentially.
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