Tetrahedron Letters p. 2455 - 2458 (1984)
Update date:2022-08-03
Topics:
Roser, Joachim
Eberbach, Wolfgang
Upon thermal activation the 1,2-epoxy-(Z)-3-hexen-5-ynes 5a-c are transformed predominantly into the 2-vinylfurans 9a-c/10a-c.A reaction mechanism is proposed which involves the transformation of 7-membered cycloallenes (structure 3) as central intermediates.
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