Journal of the American Chemical Society p. 9177 - 9181 (1992)
Update date:2022-08-03
Topics:
Petrie, Simon
Javabery, Gholamreza
Wang, Jinru
Bohme, Diethard K.
Ion-molecule addition reactions which lead to the bonding of the fullerene dications C602+ and C702+ with various neutral molecules, most notably unsaturated hydrocarbons and amines, have been studied using a SIFT apparatus at a pressure of 0.40 ± 0.01 Torr and a temperature of 294 ± 2 K. The efficiency of adduct formation in these reactions shows a dependence upon the ionization energy, the size, and the degree of unsaturation of the molecules in question. A model is presented which relates the efficiency of adduct formation to these parameters.
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