Journal of Organometallic Chemistry p. 383 - 390 (1983)
Update date:2022-08-02
Topics:
Hoberg, Heinz
Suemmermann, Klaus
Isocyanates are oxidatively coupled with imines at nickel(0) under the influence of basic chelate ligands to form diazanickelacyclopentanones.The structure of these novel five-membered nickelacycles has been determined by spectroscopic and chemical methods.The mechanism of the coupling reaction is discussed.
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