Metal-mediated reactions of α-bromomethyl-propenoate esters

Article abstract of DOI:10.1080/00397919508011363

Methyl 2-bromomethylprop-2-enoate reacts with benzaldehyde and with salicylaldehyde via its Sn and Zn complexes under aqueous conditions to form α-methylene-γ-lactones in high yields. In the case of salicylaldehyde X-ray analysis proves conclusively formation of a five- rather than a seven-membered ring. Under the above conditions 2-bromomethyl-3-phenylprop-2-enoate does not afford any cyclic products.

Full text of DOI:10.1080/00397919508011363

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Metal-Mediated Reactions of
α-Bromomethyl-Propenoate
Esters
S. E. Drewes a , R. B. Taylor a , N. S. Ramesar a & J.
S. Field a
a Department of Chemistry , University of Natal ,
Pietermaritzburg, 3200, South Africa
Published online: 23 Sep 2006.
To cite this article: S. E. Drewes , R. B. Taylor , N. S. Ramesar & J. S. Field
(1995) Metal-Mediated Reactions of α-Bromomethyl-Propenoate Esters, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 25:3, 321-329, DOI: 10.1080/00397919508011363
To link to this article: http://dx.doi.org/10.1080/00397919508011363
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