A Catalytic Method for α-Glycol Cleavage

DOI: 10.1039/c39810001232

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1232 - 1233 (1981)

Update date:2022-08-04

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Authors:

Barton, Derek H. R.

Motherwell, William B.

Stobie, Alan

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Article abstract of DOI:10.1039/c39810001232

α-Glycols are smoothly cleaved by a catalytic amount of triphenylbismuth in the presence of potassium carbonate and a little water, using N-bromosuccinimide (or another N-bromo-reagent) for the oxidation of Bi^III to Bi^V.

Full text of DOI:10.1039/c39810001232

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