Gas phase anionic ipso substitution reactions of some alkyl phenyl ethers

DOI: 10.1016/S0040-4039(00)77787-2

Source and publish data:

Tetrahedron Letters p. 1687 - 1690 (1980)

Update date:2022-08-03

Topics:

Authors:

Kleingeld

Nibbering

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)77787-2

It is shown by ¹⁸O labelling that phenoxide anions are formed both by an S_N2 and a nucleophilic aromatic substitution mechanism in the reaction of OH^- with methyl phenyl ether. These mechanisms are of minor importance in the ethyl phenyl ether system where phenoxide anions are generated almost exclusively by an E₂ mechanism.

Full text of DOI:10.1016/S0040-4039(00)77787-2

Products guided by the article

Product name:C₆H₅⁽¹⁸⁾O^(1-)

Cas No:36147-90-7

R&D Labs maybe for 36147-90-7

Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA

Relevant to this article

Doi:10.1021/ja01133a052
(1952)
Doi:10.1002/oms.1210140602
(1979)
Doi:10.1016/S0040-4039(01)97610-5
(1971)
Doi:10.1016/S0022-1139(00)83228-5
(1971)
Asymmetric synthesis of protected 2-keto-1,3-diol and 1,2,3-triol building blocks bearing a quaternary stereogenic center

Doi:10.1055/s-2001-15236
(2001)
Synthesis, characterization, and optical response of dipolar and non-dipolar poly(phenylenevinylene) dendrimers

Doi:10.1021/jo015764r
(2001)

Article Doi