Gas phase anionic ipso substitution reactions of some alkyl phenyl ethers

DOI: 10.1016/S0040-4039(00)77787-2

Source and publish data:

Tetrahedron Letters p. 1687 - 1690 (1980)

Update date:2022-08-03

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Authors:

Kleingeld

Nibbering

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Article abstract of DOI:10.1016/S0040-4039(00)77787-2

It is shown by ¹⁸O labelling that phenoxide anions are formed both by an S_N2 and a nucleophilic aromatic substitution mechanism in the reaction of OH^- with methyl phenyl ether. These mechanisms are of minor importance in the ethyl phenyl ether system where phenoxide anions are generated almost exclusively by an E₂ mechanism.

Full text of DOI:10.1016/S0040-4039(00)77787-2

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