Ring opening of cyclopropane in tricyclo[4.3.0.02,9]nonan-3-one with electrophile-nucleophile reagents

DOI: 10.1016/S0040-4020(98)01075-8

Source and publish data:

Tetrahedron p. 847 - 860 (1999)

Update date:2022-08-03

Topics:

Authors:

Fernandez-Mateos, A.

Alonso, J. J. Perez

Gonzales, R. Rubio

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Article abstract of DOI:10.1016/S0040-4020(98)01075-8

Four tricyclo[4.3.0.0^2,9]nonan-3-one systems were treated with TBDMSI, TMSTFA and TMSTFA/NaSPh, affording different cyclopropane cleavage products, depending on the location of the substituent and the nature of the reagent.

Full text of DOI:10.1016/S0040-4020(98)01075-8

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