Reactions of dimethylchloramine and ammonia-free chloramine with trialkylarsines and phenarsazines

Article abstract of DOI:10.1021/ic50112a014

The reactions of a series of trialkylarsines with chloramine and dimethylchloramine yield in every case examined the corresponding aminoarsonium chlorides. Chloramination of some 5,10-dihydrophenarsazines demonstrates that the preferred site for amination is the arsenic atom rather than the nitrogen atom. Some theoretical implications of these results are discussed.