Inorganic Chemistry p. 1226 - 1229 (1972)
Update date:2022-08-03
Topics:
Krannich, Larry K.
Sisler, Harry H.
The reactions of a series of trialkylarsines with chloramine and dimethylchloramine yield in every case examined the corresponding aminoarsonium chlorides. Chloramination of some 5,10-dihydrophenarsazines demonstrates that the preferred site for amination is the arsenic atom rather than the nitrogen atom. Some theoretical implications of these results are discussed.
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