Samarium Diiodide Mediated Reduction of Allyl Halides. A New Reductive Approach to Exomethylene Cephams.

DOI: 10.1016/S0040-4039(00)91834-3

Source and publish data:

Tetrahedron Letters p. 6931 - 6934 (1993)

Update date:2022-07-29

Topics:

Authors:

Cabri, Walter

Candiani, Ilaria

Bedeschi, Angelo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)91834-3

A new method for the synthesis of exomethylene cepham based on the use of samarium diiodide is described.The reaction proved to be chemo-, regio-, and stereo-selective affording the exomethylene cephams possessing the natural configuration at C-4 in high

Full text of DOI:10.1016/S0040-4039(00)91834-3

Products guided by the article

Product name:(6R)-3-methylene-8-oxo-7t-(2-phenoxy-acetylamino)-(6rH)-5-thia-1-aza-bicyclo[4.2.0]octane-2c-carboxylic acid methyl ester

Cas No:37787-58-9

R&D Labs maybe for 37787-58-9

Suzhou Howsine Biological Technology Co.,Ltd(expird)

website:http://www.howsine.com

Contact:86-512-67262751

Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
VanderArk International Limited

Contact:86-10-82437576

Address:Qing He
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Win-Win chemical Co.Ltd

website:http://www.win-winchemical.com

Contact:0086-577-64498589

Address:6F, No. 396 Xingping Road, Longwan Industrial Zone, Wenzhou City, Zhejiang, 325000 P.R.China
Cangzhou Senary Chemical Science-tech Co., Ltd

Contact:+86-317-3563899, 3563699

Address:168 Jinde Road, Cangzhou, Hebei, China

Relevant to this article

Ortho effect in dissociation of substituted N-phenylbenzenesulfonamides

Doi:10.1135/cccc20011380
(2001)
3-N-substituted aminomethyl derivatives of rifamycin SV. A convenient method of synthesis, cyclization of certain derivatives, and anticellular and antiviral activities of several derivatives

Doi:10.1021/jm00220a009
(1977)
Doi:10.1021/ja01119a069
(1953)
Doi:10.1021/ja00769a024
(1972)
Asymmetric synthesis of γ-keto-δ-lactam derivatives: Application to the synthesis of a conformationally constrained surrogate of ala-ser dipeptide

Doi:10.1021/jo0159688
(2001)
Evaluating the reactivity and stereoselectivity of salicyl-type thioglycosides as non-malodorous thioglycoside alternatives for oligosaccharide synthesis

Doi:10.1080/07328303.2021.1921787
(2021)

Article Doi