Samarium Diiodide Mediated Reduction of Allyl Halides. A New Reductive Approach to Exomethylene Cephams.

DOI: 10.1016/S0040-4039(00)91834-3

Source and publish data:

Tetrahedron Letters p. 6931 - 6934 (1993)

Update date:2022-07-29

Topics:

Authors:

Cabri, Walter

Candiani, Ilaria

Bedeschi, Angelo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)91834-3

A new method for the synthesis of exomethylene cepham based on the use of samarium diiodide is described.The reaction proved to be chemo-, regio-, and stereo-selective affording the exomethylene cephams possessing the natural configuration at C-4 in high

Full text of DOI:10.1016/S0040-4039(00)91834-3

Products guided by the article

Product name:(6R)-3-methylene-8-oxo-7t-(2-phenoxy-acetylamino)-(6rH)-5-thia-1-aza-bicyclo[4.2.0]octane-2c-carboxylic acid methyl ester

Cas No:37787-58-9

R&D Labs maybe for 37787-58-9

Penglai Qianwei Chemical Co., Ltd.

Contact:86-535-3357802

Address:Shahelu (north), Penglai, Shandong, China
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang

Relevant to this article

Ortho effect in dissociation of substituted N-phenylbenzenesulfonamides

Doi:10.1135/cccc20011380
(2001)
3-N-substituted aminomethyl derivatives of rifamycin SV. A convenient method of synthesis, cyclization of certain derivatives, and anticellular and antiviral activities of several derivatives

Doi:10.1021/jm00220a009
(1977)
Doi:10.1021/ja01119a069
(1953)
Doi:10.1021/ja00769a024
(1972)
Asymmetric synthesis of γ-keto-δ-lactam derivatives: Application to the synthesis of a conformationally constrained surrogate of ala-ser dipeptide

Doi:10.1021/jo0159688
(2001)
Evaluating the reactivity and stereoselectivity of salicyl-type thioglycosides as non-malodorous thioglycoside alternatives for oligosaccharide synthesis

Doi:10.1080/07328303.2021.1921787
(2021)

Article Doi