Tetrahedron p. 349 - 358 (1998)
Update date:2022-07-30
Topics:
Mahmood, Syed J.
Saha, Anjan K.
Mahmun Hossain
The iron Lewis acid 1 was found to catalyze reactions of phenyldiazomethane and aromatic aldehydes to give cis-epoxides along with the corresponding ketones. The yield of the epoxide increased with electron- withdrawing substituents on the aldehyde, while little or no epoxide was formed with electron-donating substituents. The reaction was found to go through the coordination of the aldehyde to the iron Lewis acid instead of a carbene intermediate.
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Doi:10.1021/acs.orglett.8b01692
(2018)Doi:10.1007/BF00771581
()Doi:10.1016/S0020-1693(01)00543-6
(2001)Doi:10.1021/ol036157o
(2004)Doi:10.1039/DT9880000509
(1988)Doi:10.1246/cl.2001.1096
(2001)
