Chemistry Letters p. 1060 - 1061 (2001)
Update date:2022-08-04
Topics:
Inoue, Yoshihisa
Nakano, Takashi
Tanaka, Hidetsugu
Kashiwa, Norio
Fujita, Terunori
Two new titanium complexes having two phenoxy-pyridine chelate ligands were synthesized and investigated for their potential as ethylene polymerization catalysts. On activation with Ph3C+B-(C6F5) 4/ i-Bu3Al, one of the complexes, bis[2-(2′-pyridyl)phenolato] titanium complex, exhibited high activity (227-564 kg-PE/mol-cat·h) and produced high molecular weight polyethylene (Mr; 140000-3230000) at 25-75°C.
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