SILYLCUPRATION OF ACETYLENES

DOI: 10.1016/0022-328X(86)80494-6

Source and publish data:

Journal of Organometallic Chemistry p. 255 - 260 (1986)

Update date:2022-08-05

Topics: Catalyst Acetylenes Silyl group

Authors:

Chen, Hsiao-Ming

Oliver, John P.

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Article abstract of DOI:10.1016/0022-328X(86)80494-6

Several organosilylcuprates have been prepared and their reactions with acetylenes examined.It has been shown that LiCu2 adds to acetylenes in only one manner, i.e. with cis addition and the Si(SiMe3)3 group in the least hindered cite as shown

Full text of DOI:10.1016/0022-328X(86)80494-6

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