Helvetica Chimica Acta p. 1031 - 1038 (1983)
Update date:2022-08-02
Topics: Yield Purification Reaction Conditions Preparation Substrate Fragmentation Cyclopentenyl
Snowden, Roger L.
The potassium 2-substituted bicyclo<2.2.1>hept-5-en-2-alkoxides derived from alcohols 2-9 at 30 deg C in hexamethylphosphoric triamide (HMPA) afford 1-(3'-cyclopentenyl)-2-alkanones 10-19 via heterolytic C(1),C(2)-allylic bond cleavage in the substrate alkoxide followed by intramolecular protonation of the resultant transient allylic anion.
View MoreJiYi Chemical (Beijing) Co., Ltd.
Contact:+86-10-89385733
Address:Shilou Town of Fangshan District， Beijing
website:http://www.vanzpharm.com/en/index.html
Contact:86-27-84492310
Address:FANHU INDUSTRY PARK
Wuxi Forest Biological Co.,Ltd
Contact:+86-510-81602300
Address:Room 317,Building D, No.159 middle Chengjiang Road,Jiangyin Wuxi city.
Nanjing Habo Medical Technology Co., Ltd.
Contact:025－85769882
Address:No.108. Ganjiabian east. Qixia District .Nanjing
Zhuhai Biliantian Bio-Tech Co., Ltd.(expird)
Contact:0756-7716996
Address:Gongyuan Raod,Zhuhai,Guangdong Prov.China.
Doi:10.1021/ja012046d
(2001)Doi:10.1016/j.jorganchem.2016.08.031
(2016)Doi:10.1021/ja01150a020
(1951)Doi:10.1021/ic000500t
(2001)Doi:10.1021/ja00259a060
(1987)Doi:10.1016/j.bmcl.2015.06.069
(2015)
