Helvetica Chimica Acta p. 1031 - 1038 (1983)
Update date:2022-08-02
Topics: Yield Purification Reaction Conditions Preparation Substrate Fragmentation Cyclopentenyl
Snowden, Roger L.
The potassium 2-substituted bicyclo<2.2.1>hept-5-en-2-alkoxides derived from alcohols 2-9 at 30 deg C in hexamethylphosphoric triamide (HMPA) afford 1-(3'-cyclopentenyl)-2-alkanones 10-19 via heterolytic C(1),C(2)-allylic bond cleavage in the substrate alkoxide followed by intramolecular protonation of the resultant transient allylic anion.
View MoreShandong Xingshun New Material Co., Ltd.
website:http://www.sd-xingshun.com
Contact:+86-519-86461196
Address:Middle of Luhua East Road, Dingtao District
Taizhou Crene Biotechnology co.ltd
Contact:86-576-88813233 88205808
Address:Economic Developed Zone of Taizhou Zhejiang China
Guangxi Shanyun Biochemical Science and Technology Co., Ltd
Contact:+86-0772--6828887
Address:#2 Industrial Park of Luzhai County, Liuzhou, Guangxi, China
ShangHai Soyoung Biotechnology Inc
website:http://www.soyoungbio.com
Contact:+86-21-69893009
Address:shanghai
Jiangxi Hessence Chemicals Co., Ltd.
Contact:+86 796 3511924
Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
Doi:10.1021/ja012046d
(2001)Doi:10.1016/j.jorganchem.2016.08.031
(2016)Doi:10.1021/ja01150a020
(1951)Doi:10.1021/ic000500t
(2001)Doi:10.1021/ja00259a060
(1987)Doi:10.1016/j.bmcl.2015.06.069
(2015)
