Synthesis of symmetrical and unsymmetrical 1,2-Diketones through cathodic intramolecular coupling of diesters

DOI: 10.1016/S0040-4039(97)01573-6

Source and publish data:

Tetrahedron Letters p. 6717 - 6720 (1997)

Update date:2022-07-30

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Authors:

Kashimura, Shigenori

Murai, Yoshihiro

Washika, Chise

Yoshihara, Daisuke

Kataoka, Yasuki

Murase, Hiroaki

Shono, Tatsuya

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Article abstract of DOI:10.1016/S0040-4039(97)01573-6

Electroreduction of diesters [R¹COO(CH₂)₂OCOR₂] with Mg electrode has been found to give the corresponding unsymmetrical 1,2-Diketones (R¹COCOR²) with excellent yields.

Full text of DOI:10.1016/S0040-4039(97)01573-6

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