Highly diastereoselective addition reaction of ketene silyl acetals to imines catalyzed by samarium(III) iodide

DOI: 10.1246/cl.1999.591

Source and publish data:

Chemistry Letters p. 591 - 592 (1999)

Update date:2022-08-04

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Authors:

Hayakawa, Ryuuichirou

Shimizu, Makoto

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Article abstract of DOI:10.1246/cl.1999.591

In the presence of a catalytic amount of a samarium(III) iodide, the addition reaction of ketene silyl acetal to imine afforded the corresponding β-aminoester with high antiselectivity. The reaction of chiral imine under the same conditions gave β-aminoes

Full text of DOI:10.1246/cl.1999.591

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