Kinetics and Deuterium Kinetic Isotope Effects for the Thermal Sigmatropic Rearrangements of cis,cis-1,3,5-Octatriene

DOI: 10.1021/ja00260a017

Source and publish data:

Journal of the American Chemical Society p. 8051 - 8056 (1987)

Update date:2022-08-03

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Authors:

Baldwin, John E.

Reddy, V. Prakash

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Article abstract of DOI:10.1021/ja00260a017

Thermal isomerizations of cis,cis-1,3,5-octatriene at 60-111 deg C occur with activation parameters log A = 9.1 and E_a = 21.3 (to cis,cis,cis-2,4,6-octatriene) and E_a = 20.2 kcal mol^-1 (to cis,cis,trans-2,4,6-octatriene).P

Full text of DOI:10.1021/ja00260a017

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