Tetrahedron p. 2967 - 2975 (1980)
Update date:2022-07-28
Topics:
Montheard
Camps
Ait-Yahia
Guilluy
Perchloric acid in acetic acid reacts with phenylacetylene to yield acetophenone α-chloroacetophenone, αα'-dichloroacetophenone, α-acetoxy-α'-chloroacetophenone, dichloroαβstyrene and β-chlorophenylacetylene. The disappearance rate of phenylacetylene is proportional to the concentrations of phenylacetylene and perchloric acid; that of perchloric acid varies in proportion to the amount of phenylacetylene and perchloric acid. Rate constants are in a ratio 2.5:1. The various chlorinated products arise from acetyl perchlorate.
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